Ukraine's President Volodymyr Zelenskyy said talks with Russia on getting wounded defenders out of the Azovstal plant in Mariupol were very complex, adding Kyiv was using influential intermediaries.
Russian forces have been constantly bombarding the steelworks in the southern port of Mariupol, the last bastion of hundreds of Ukrainian defenders in a city almost completely controlled by Russia after more than two months of a siege.
Ukraine, saying there is no military solution to the standoff, has proposed evacuating 38 of the most severely wounded defenders. If Moscow allows them out, Kyiv says it will release a number of Russian prisoners of war.
"At the moment very complex negotiations are underway on the next phase of the evacuation mission – the removal of the badly wounded, medics. We are talking about a large number of people," Mr Zelenskyy said in a late-night address.
"Of course, we are doing everything to evacuate all the others, every one of our defenders. We've already involved everyone around the world who could be the most influential intermediaries," he added, without giving details.
Russia, which had initially insisted the defenders give themselves up, has said little publicly about the talks.
Many of those still in the plant are members of the Azov Regiment. Deputy commander Sviatoslav Palamar on Friday said his forces would continue to resist as long as they could.
"We have a problem with ammunition, with food, with water, with medicines," he told an online forum streamed on YouTube.
"Our enemy, supported by planes and artillery, continues to attack. They continue their assault on our positions but we continue to repel them," Mr Zelenskyy said, calling on the United States to help evacuate the wounded fighters.
Ukrainian Deputy Prime Minister Iryna Vereshchuk earlier said the results of the talks "may not be to everyone's liking, but our task is to evacuate our boys. All of them. Alive."
Meanwhile, Ukrainian forces destroyed parts of a Russian armoured column as it tried to cross a river in the Donbas region, a video from Ukraine's military showed on Friday.
"We are entering a new, long phase of the war," Ukrainian Defence Minister Oleksii Reznikov said in a Facebook post, predicting "extremely tough weeks" ahead, during which he said Ukraine would largely be alone against an "enraged aggressor".
Ukrainian forces have driven Russia from the second-largest Ukrainian city of Kharkiv in their fastest advance since Kremlin troops pulled away from Kyiv and the northeast over a month ago to focus their offensive on the Donbas region bordering Russia.
The city, which had been under fierce bombardment, has been quiet for at least two weeks and Reuters journalists have confirmed Ukraine now controls territory stretching to the Siverskyi Donets River, around 40 km to the east.
However, Moscow is still bombarding villages north of Kharkiv.
Some 10 km north of the city, firefighters doused smouldering wreckage in Dergachi after what local officials said was an overnight Russian missile attack on the House of Culture, used to distribute aid. Volunteers inside were trying to salvage packages of baby diapers and formula.
"I can't call it anything but a terrorist act," the mayor, Vyacheslav Zadorenko, told Reuters. "They wanted to hit the base where we store provisions and create a humanitarian catastrophe."
Another missile had slammed into the building on Thursday and Russian shelling had wounded a staff member at a clinic and killed a young couple in their home, he said.
Russia, which denies targeting civilians, said its forces had shot down a Ukrainian Su-27 aircraft in the Kharkiv region and disabled the Kremenchuk oil refinery in central Ukraine.
It was not immediately possible to verify the reports.
Britain said Ukraine had stopped Russian forces, southeast of Kharkiv, crossing the Siverskyi Donets river, west of Severodonetsk.
Footage released by Ukrainian Airborne Forces Command appeared to show several burnt-out military vehicles near segments of a partially submerged bridge and many other damaged or abandoned vehicles, including tanks, nearby.
Reuters could not immediately verify the report, or when or where the clash took place.
The Kremlin calls its 24 February invasion of Ukraine a "special military operation" to demilitarise a neighbour threatening its security. Ukraine says it poses no threat to Russia and that the deaths of thousands of civilians and destruction of cities and towns show Russia is waging a war of aggression.
In their first conversation since the invasion, US Defense Secretary Lloyd Austin spoke by telephone on Friday with Russian Defence Minister Sergei Shoigu, seeking an immediate ceasefire and stressing the importance of open lines of communication.
Olena Trinus, 62, at her home which was destroyed during the Russian invasion in Irpin, Kyiv Oblast on May 13, 2022. Trinus built the house with her husband who died in 2020. Source: AAP / AP
Kyiv says children deported
Ukraine accused Russia of forcibly deporting more than 210,000 children since its invasion, saying they were among 1.2 million Ukrainians transferred against their will.
The Kremlin says people have come to Russia to escape fighting.
In Kyiv, a court began hearing the first case of what Ukraine says are more than 10,000 possible war crimes.
A Russian soldier is accused of murdering a civilian. Moscow has accused Kyiv of staging such crimes.
In Mariupol, Russian forces intensified their bombardment of the Azovstal steelworks, as some of the civilians evacuated recently from tunnels under the plant where they sheltered described terrifying conditions.
"Every second was hellish," 51-year-old nurse Valentyna Demyanchuk told Reuters.
Around Snake Island, which Ukrainian military intelligence said allows control of civilian shipping, renewed fighting could help Kyiv resume grain exports vital to world supplies.
Ukraine said it had damaged a Russian navy logistics ship near Snake Island. Russia's defence ministry did not respond to a request for comment.
Satellite imagery from Maxar, a private US-based company, showed the aftermath of what it called probable missile attacks on a Russian landing craft near the island.
Meeting in Germany, foreign ministers from the G7 group of rich nations backed giving Ukraine more aid and arms and the European Union's foreign policy chief Josep Borrell announced a further 500 million euros ($520 million) worth of military support that should be approved next week by EU members.
He voiced confidence the bloc will agree on an embargo on Russian oil.
Ukraine's foreign minister told the meeting he hoped EU holdout Hungary would agree to the oil embargo.
Hungarian Prime Minister Viktor Orban wants hundreds of millions of dollars in compensation before agreeing to a ban.
In his late-night video address, Mr Zelenskyy said the Russian invasion could cause famine in dozens of countries, triggering political instability and migration.
"How much would you then have to spend to overcome the consequences? These are the questions which should be answered by those who are dragging their feet on sanctions against Russia or are trying to delay aid for Ukraine," he said.
A day after Finland committed to applying to join NATO, Swedish Foreign Minister Ann Linde said membership for her country would bring stability and benefit countries around the Baltic sea.
Joining the 30-nation Western military alliance would end the neutrality the two states maintained during the Cold War and further expand NATO, something Russian President Vladimir Putin said his invasion of Ukraine aimed to prevent.