A Russian missile attack on a large Ukrainian military facility near the border with NATO member Poland on Sunday killed nine people and wounded 57, Ukrainian officials said.
Foreign military instructors have previously worked at the base, Ukraine said. It was not clear whether any were there at the time.
Regional governor Maksym Kozytskyy said Russian planes fired around 30 rockets at the Yavoriv International Center for Peacekeeping and Security, adding that some were intercepted before they hit.
The 360 square-kilometre facility, less than 25 kilometres from the Polish border, is one Ukraine's biggest and the largest in the western part of the country.
Reuters was unable immediately to verify the report. The Kremlin did not immediately reply to a request for comment on the missile strike so close to the border with NATO.
Nineteen ambulances with sirens on were seen by Reuters driving from the direction of the Yaroviv facility after the strike and and black smoke rose from the area.
"Russia has attacked the International Center for Peacekeeping & Security near Lviv. Foreign instructors work here. Information about the victims is being clarified," Ukrainian Defence Minister Oleksii Reznikov said in an online post.
A Ukrainian defence ministry representative told Reuters the ministry was still trying to establish if any foreign instructors were at the centre at the time of the attack.
Ukraine held most of its drills with NATO countries there before the invasion. The last major exercises were in September.
The mayor of another city in western Ukraine, Ivano-Frankivsk, said Russian troops also continued to hit its airport, with no initial reports of casualties.
It comes as Ukraine prepared on Sunday for a "relentless defence" of Kyiv as the capital faced possible encirclement by advancing Russian forces who have also kept up a bombardment of the besieged southern port city of Mariupol.
In a video address posted on social media late Saturday night, President Volodymyr Zelenskyy said nevertheless the Russians did not have the strength or spirit to conquer Ukraine.
"The Russian invaders cannot conquer us. They do not have such strength. They do not have such spirit. They are holding only on violence. Only on terror. Only on weapons, which they have a lot," he said.
A convoy of humanitarian aid headed for Mariupol had been blocked at a Russian checkpoint, but it was hoped it could reach the city Sunday, Deputy Prime Minister Iryna Vereshchuk said.
'Humanitarian catastrophe'
The strategic port, in particular, is facing what Ukraine says is a "humanitarian catastrophe", with more than 1,500 civilians killed.
Attempts to evacuate hundreds of thousands of civilians have repeatedly failed.
A top Russian officer described the situation in stark language.
"Unfortunately, the humanitarian situation in Ukraine is continuing to deteriorate rapidly, and in some cities, it has reached catastrophic proportions," said the head of the Russian National Defence Control Centre, Mikhail Mizintsev.
In his video address, Mr Zelenskyy appealed for more aid.
"I keep reiterating to our allies and friends abroad; they have to keep doing more for our country, for Ukrainians and Ukraine. Because it is not only for Ukraine, but it is for all of Europe," he said.
A 'city under siege'
The Russians have advanced far enough to raise fears of Kyiv becoming encircled imminently.
Other cities have already fallen or been surrounded since Russia invaded its neighbour on 24 February, with civilians targeted in what the United Nations warned could amount to war crimes.
The key southern port of Odesa was preparing for an offensive by Russian troops, who were concentrating about a hundred kilometres to the east in the city of Mykolaiv.
Mykolaiv, which lies on the road to the strategic port city, has been under attack for days, and an AFP reporter said a hospital there came under fire.
Satellite imagery of Mariupol Hospital after an attack in Mariupol, Ukraine, 12 March 2022. Source: Getty / (c) 2022 Maxar Technologies
He claimed Russia had lost about 12,000 troops while Moscow, for its part, has only given a toll of 498 dead, released on 2 March.
At least 579 civilians have been killed, according to a tally Saturday by the United Nations, which stressed that its figures were probably much lower than reality.
The United Nations estimates that almost 2.6 million people have fled Ukraine since the invasion, most of them to Poland, in Europe's worst refugee crisis since World War II.
In Kyiv, only the roads to the south remain open and the city is preparing to mount a "relentless defence", according to the Ukrainian presidency.
Kyiv Mayor Vitali Klitschko said the capital, described by a senior Ukrainian official Friday as a "city under siege", was reinforcing defences and stockpiling food and medicine.
Britain's ministry of defence estimated that Russian forces were about 25 kilometres from the capital on Saturday and that a column north of the city had dispersed, reinforcing the indication of an attempt to encircle it.
Ukrainian soldiers said they believe the Russians have overestimated their resources, in terms of troops and equipment, and underestimated those of their opponent.
"They have to camp in villages in temperatures of nearly minus 10 Celsius at night. They lack provisions and have to raid houses," said one soldier, Ilya Berezenko, 27.
Diplomacy efforts continue
Intense efforts at diplomacy continued, with the leaders of France and Germany, Emmanuel Macron and Olaf Scholz, urging Russian counterpart Vladimir Putin during a three-way phone conversation on Saturday to end the deadly blockade, Paris said.
Facing growing international condemnation, Mr Putin sought to turn the tables, slamming Kyiv for what he described as the "flagrant violation" of international humanitarian law and accusing Ukraine's army of executing dissenters and using civilians as hostages.
The French presidency denounced his accusations, made during the talks with Mr Macron and Mr Scholz, as "lies".
But in a small glimmer of hope, Mr Zelenskyy said Saturday that Russia - after appearing unbudging for days - had adopted a "fundamentally different approach" in the latest talks to end the conflict.
He told reporters he was "happy to have a signal from Russia" after Mr Putin spoke of "some positive shifts" in a near-daily dialogue.
As Russia widens its bombardment, Mr Zelenskyy's pleas for help have grown increasingly desperate.
Washington and its EU allies have sent funds and military aid to Ukraine and taken action against Russia's economy and oligarchs. A cultural and sporting boycott has further isolated Moscow.
As international sanctions against Moscow have steadily tightened, crippling Russia's economy, the country's space agency Roscosmos warned Saturday that the International Space Station could crash if Russian spacecraft serving it are affected.
But Washington on Friday added still more layers of sanctions, this time ending normal trade relations and announcing a ban on Russian vodka, seafood and diamonds.
This photograph taken on 4 March, 2022 shows a school building damaged in shelling in the city of Chernihiv, Ukraine. Source: Getty / DIMITAR DILKOFF
But he has ruled out direct action against nuclear-armed Russia, warning that it would lead to "World War III".
'Desperate' situation in Mariupol
The situation in Mariupol remains "desperate", according to Doctors Without Borders, with no water or heating - and food supplies dwindling.
"Hundreds of thousands of people... are for all intents and purposes besieged," Stephen Cornish, one of those heading the medical charity's Ukraine operation, told AFP.
He called sieges "a medieval practice" long outlawed.
Foreign combatants have entered the conflict on both sides, and on Friday, the Kremlin ramped up efforts to bring in reinforcements, particularly from Syria.
In the Russian-held city of Melitopol, Mr Zelenskyy said, 2,000 people protested against the kidnapping Friday of the mayor by Russian troops.
He called on Mr Macron and Mr Scholz to help secure Ivan Fedorov's release, which he said opened a "new stage of terror".
